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 Vol. 47, No. 2 (2010)

CONTENTS


RADIOCHEMICAL STUDY ON PHOTONUCLEAR REACTION MECHANISM AT INTERMEDIATE ENERGIES UPTO 1.2 GeV


Koh Sakamoto

67

Felicitation Full text

An account is given on radiochemical investigations on photonuclear reactions on target nuclei ranging from 7Li to 209Bi at intermediate energies up to 1.2 GeV, with use of bremsstrahlung beams of its maximum end-point energies of E0 = 30–1200 MeV with small steps of E0, by the authors group since 1980s. The investigation covers the yield measurements of spallation, fragmentation, fission of the preactinides, 197Au and 209Bi, and photopion reactions, systematically performed with respect to photon energy (E0 and/or k) target mass (At) and/or target composition (N/Z)t, product mass (A) and product composition (N/Z). The analyses of the thousands of yield data obtained with aids of intensive chemical processings have yielded valuable insights into the reaction mechanism, i.e. characteristics of Δ-resonance and strong effects of nuclear medium. In addition, a simple recoil experiment resulted valuable kinematic information regarding to the reaction steps. All of the results have updatedly used to test Monte Carlo calculations based on the photon-induced intranuclear cascade and evaporation analysis (PICA) code and its improved versions and the degrees of the validity of the codes have been demonstrated. New implications for the nuclear structure and reaction mechanism have been discussed by referring to the nuclear models on which the calculations are based.


BARRIERS AGAINST IMPLEMENTING AND MANAGING QUALITY IN INFORMATION TECHNOLOGY  INDUSTRY OF PAKISTAN


A. Ahsan

91

Full text

This research paper presents major barriers to implement quality in IT sector of Pakistan. The paper not only explores (exploration w.r.t quality management covering discussion like what is done, what is not done, what are the loopholes, what must be done and / or what must not be done), but also presents detailed explanation of the main highlights by performing necessary qualitative analysis. In addition to exploration and explanation of barriers (the paper specifically talks of barriers concerning behavior, management and culture) to quality within IT sector of Pakistan, the paper also explains all the important issues arising due to the deprived quality management. As a result of detailed analysis performed, the paper finally identifies important remedies for revitalization of quality management function as recommendations. Mainly, exploration, explanation and analysis of reasons and remedial actions are focused. Discussion and analysis is limited to behavioral, cultural and managerial perspective.


* Corresponding author : shakir@pinstech.org.pk

MONTE CARLO STUDY OF Ar+ INDUCED KINETIC ELECTRON EMISSION FROM MgO THIN FILM


Shakir Ullah , A.H. Dogar and A. Qayyum

125

Full text

A Monte Carlo program has been developed to investigate the electron emission from 5000 Å thick MgO film for impact of Ar+ ions having energies in the range of 50 to 1000 eV. The program incorporates the excitation of target electrons by projectile ions, recoiling target atoms and fast primary electrons. It can be used to calculate the kinetic electron yield, distribution of the electron excitation points in the solid and other physical parameters of the emitted electrons. The calculated electron emission yield is compared with the available experimental data, considering the effect of potential emission a good agreement is found. In addition, the effect of projectile energy and incident angle on the longitudinal distribution of the excitation points of electrons emitted from MgO thin film is investigated.


* Corresponding author : miqbalchishti@yahoo.com

THERMAL PROPERTIES AND ACTIVATION ENERGY OF THE [ZR0.645NI0.155AL0.115CU0.085]98Si2 AMORPHOUS ALLOY


M. Iqbal , J.I. Akhter and Z.Q. HU

131

Full text

Zr-based amorphous alloys are novel materials having wide range of applications. Melt spun amorphous ribbon with composition (Zr0.645Ni0.155Al0.115Cu0.085)98Si2 of 50 mm thickness was synthesized to investigate the thermal properties and activation energy. Differential scanning calorimetry (DSC) was used to investigate these properties. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed for phase analysis and microstructural study. Thermal parameters were derived from DSC measurements. Phases like NiZr2, CuZr2 and SiZr2 were identified in the samples annealed at various temperatures. It was found that Si addition had positive effect on most of the thermal parameters.


PARTICLE SIZE EFFECT ON MAGNETIC AND TRANSPORT PROPERTIES OF  La0.7Ca0.3MnO3 NANOPARTICLES


S. Qaseem , K. Maaz , A. Mumtaz and S.K. Hasanain

137

Full text

La0.7Ca0.3MnO3 nanoparticles have been synthesized by modified citrate route with particle sizes of 20, 26 and 32 +3 nm respectively. The structural characterization has been performed by XRD and TEM analyses while magnetic characterization has been performed by vibrating sample magnetometer (VSM). This work presents the study of size effects on magnetic and electrical properties of Ca-doped CMR nanoparticles (La0.7Ca0.3MnO3). Different particle sizes have been prepared by a wet chemical route. Magnetic characterization reveals that magnetization increases with the increase in the particle size and the magnetic transition temperature for larger particles is the same as in the bulk (258K). The ferromagnetic and resistive transitions are however broad compared to the case of bulk presumably due to the role of the surface. The metal-insulator transition temperature is found to be at 158K while the resistivity shows anomalous low temperature behavior with an upturn at low temperatures presu due to coulomb blockade effects. Furthermore, the field dependence of the resistivity displays nonmonotonic behavior and is explained in terms of the field assisted tunneling between grains.


ADSORPTION CAPACITY OF ACTIVATED CHARCOAL FOR LANTHANIDES (III) IONS


R. Qadeer , M. Saleem and N. Khalid

143

Full text

The adsorption of lanthanides metals namely Sm3+, Eu3+ and Gd3+ on activated charcoal has been studied as a function of pH at room temperature. Maximum adsorption was observed at pH value of 4. The adsorption mechanism has been described in term of hydrolysed species formed in aqueous solution at different pH. The adsorption of metal ions obeyed the Langmuir and Temkin isotherm models in the range of 1.0 to 6.0 g of metal ions per liter of solution. The values of adsorption capacities “Q” for Sm3+, Eu3+ and Gd3+ ions have been calculated at different pH. The adsorption capacities obtained from Langmuir model are in agreement with the determined values of Temkin constants “AT” from Temkin model. The determined adsorption capacities of the investigated metal ions varied in the order of Gd3+ > Eu3+ > Sm3+ ions and were correlated with the charge density (Z/r) of the metal ions studied.


GAMMACAL – A USEFUL COMPUTER PROGRAM FOR NEUTRON ACTIVATION ANALYSIS AND RADIOACTIVITY CALCULATIONS


M. Wasim

149

Full text

GAMMACAL is a computer program with graphical user interface for the calculation of radionuclide activity of gamma emitting radionuclides and elemental concentration using neutron activation analysis data. The software has been tested and is in use for the last ten years. It provides not only concentrations but also quality control data. The program is available for free of cost on writing request to the author.


* Corresponding author :  mwasim@pinstech.org.pk

DATA ANALYSIS OF THE RESULTS SUBMITTED IN THE PROFICIENCY TEST OF IAEA-CU-2006-06 (ANCIENT CHINESE CERAMIC) – MORE DATA INPUT USING K0-INAA


M. Wasim , M. Arif and J. H. Zaidi

153

Full text

In the first part of this paper, the data submitted in the proficiency test (PT) conducted under the IAEA co-ordinated research project has been statistically evaluated. The data contains elemental concentrations determined in the IAEA-CU-2006-06 (ancient Chinese ceramic) powder by different laboratories using various analytical techniques. The analysis has been performed by using relative deviation and relative standard deviation. The use of rescaled sum of z-score, sum of square of z-score and principal component analysis has been suggested to determine the overall laboratory performance. The second part of the paper provides elemental concentrations of four elements (Eu, Lu, Sr and Zr) determined by our laboratory by k0-INAA. Finally, principal component analysis has been applied to get inter-laboratories patterns on the scores plot. The overall analysis reveals that INAA produces results with high accuracy and precision and with good sensitivity for a large number of elements.


INVESTIGATION OF THE MINERAL CONTENTS OF SOME VARIETIES OF POWDER MILK BY PIXE


N. Ahmed , S.M.H. Aejaz , A. Naeem, M. Shahnawaz and S. Saadat

161

Full text

Milk and milk products constitute an important ingredient of human nutrition all over the world. Macro mineral contents like sodium, potassium, calcium, phosphorus and micro mineral contents like iron, copper, zinc, manganese of some varieties of powder milk available in the local market have been investigated by Proton Induced X-Ray Emission (PIXE). These elements are essential for the optimal functioning of various chemical processes taking place in the human body. Any toxic element present in milk can also be detected simultaneously. PIXE is a powerful and universal elemental analysis technique with high detection sensitivity for elements with Z> 11 in the periodic table. The technique is non-destructive and may be applied to samples as small as a cell to a large painting.


DISINFECTION OF MUNICIPAL WATER USING SOLAR RADIATION: AN ECONOMICAL APPROACH FOR RURAL DWELLERS IN THE COASTAL REGION OF KARACHI


M.F. Ahmed and M. Saleem

165

Full text

At present acquiring safe drinking water in rural or remote areas of Pakistan is a challenging task for dwellers. Coast line of Karachi is a sporadic habitat of villages not having access to safe drinking water. Many incidents of waterborne diseases have been reported in that area and attributed to contaminated municipal water supply. Solution of the problem is disinfection however, general methods of water disinfection such as boiling, UV-lamp, ozonation and chemical additive are costly or require skilled manpower. Present study investigates the solar disinfection method to treat municipal water supply at Karachi Institute of Power Engineering (KINPOE) located at the costal belt of Karachi. Effect of exposure time, bottle material and turbidity of water on the process performance was evaluated. Model indicator bacteria total coliform (TC) was used to evaluate the solar disinfection process. Study revealed that in order to disinfect the municipal water, samples should be filled in PET transparent bottles, having turbidity below 23 NTU, and expose to solar radiation in the study area at least for one hour. Study shows that solar disinfection may provide safe drinking water meeting national and international water quality standards at minimum cost and effort in sunshine rich areas and not having access to other water purification systems.


* Corresponding author : azhar@pinstech.org.pk

BACTERIOLOGICAL (FECAL AND TOTAL COLIFORM) QUALITY OF PAKISTANI COASTAL WATER


A. Mashiatullah , R. M. Qureshi , T. Javed, M. S. Khan, M. Z. Chaudhary and F. Khalid

173

Full text

The coliform bacteria group consists of several genera of bacteria belonging to the family enterobacteriaceae. These are harmless bacteria, mostly live in soil, water, and digestive system of animals. Fecal coliform bacteria, which belongs to this group, are present in large numbers in feces and intestinal tract of human beings and other warm-blooded animals which can enter into water bodies from human and animal waste. Swimming in water having high levels of Fecal coliform bacteria increases the chance of developing illness (fever, nausea or stomach cramps) from pathogens entering the body through mouth, nose, ears or cuts in the skin. The objective of the present study was to characterize the bathing quality of Pakistani coastal water with respect to coliform bacteria. Total and Fecal coliform bacteria were determined at seven (7) different locations along Pakistan coast using membrane filtration (MF) technique. 100 ml of water was passed through 0.45 micron (m) filter paper. These filter papers were put on pads, soaked in Lauryle sulphate broth in petri-dishes and incubated at 44oC for Fecal and 37oC for Total coliform for 24 hours. Significantly high population of Fecal and Total coliform bacteria was recorded at Karachi harbour area and Indus delta region. Results indicate that a large amount of domestically originated waste is being discharged into these locations without any pre-treatment (e.g., screening, activated sludge, by using filtration beds etc.) resulting in a poor seawater quality making it unfit for bathing.